If a package contains hazardous materials it must be declared on the carrier label.
The only hazmat setting that can be electronically submitted to the carrier is defined in the package option:
This can be set to ORMD or LIMITED_QUANTITY. This is a per package option, so make sure that it is filled in for each package that contains hazardous material.
In addition, the appropriate hazmat sticker must be on the package along with a printed copy of the accompanying hazmat documentation. This report is not standardized and varies widely from country to country, so it is not included in DShip. If you have WMDM installed it has a sample hazmat sticker (report 23044528) that your NAV partner can help you customize to your needs.